In view of the needs of urban underground long tunnel pavement, the new material AC-20C low-temperature composite modified asphalt mixture used in the tunnel pavement of the east section of Beiheng Passage is studied from the aspects of raw materials, mix proportion design, gas emission of construction mixture, and on-site physical detection. The optimal mixture gradation and optimal asphalt-aggregate ratio are determined according to different gradations and different asphalt-aggregate ratios. The water stability, rutting resistance and crack resistance of asphalt mixture are evaluated through the residual stability, dynamic stability, freeze-thaw splitting strength ratio and low-temperature bending failure strain test. At the same time, by comparing the energy consumption and gas emissions of low-temperature and traditional hot-mixed asphalt mixtures, the situation of energy conservation and emission reduction is analyzed. The results show that the optimal asphalt-aggregate ratio of this mix proportion design is 4.2%, the dynamic stability is ≥2 400 times/mm, and the residual stability, freeze-thaw splitting strength ratio, low-temperature bending test failure strain, as well as on-site compaction degree and water seepage indicators all meet the design requirements, and the physical application effect is good. At the same time, for every ton of low-temperature asphalt mixture produced by the mixing plant, 0.9 cubic meters of natural gas can be saved, and the reduction rate of relevant gas emissions can reach more than 40%, which fully demonstrates the concept of energy conservation and emission reduction of low-temperature environmentally friendly modified asphalt.